PHOTODEGRADATION OF BATIK DYE COLOUR INDIGOSOL YELLOW IRK USING ZNO-CHITOSAN COMPOSITE
DOI:
https://doi.org/10.23960/analit.v9i01.187Keywords:
Indigosol Yellow IRKAbstract
This experiment research aims to determine the optimum conditions for degradation of Indigosol Yellow IRK batik dye using ZnO-Chitosan composite, including radiation time, dye concentration, pH and determining the effectiveness of degradation. Synthesis of ZnO-chitosan composite using wet impregnation method. Radiation time with variations in time of 10, 30, 60, 120, and 180 minutes, variation in dye concentration 50, 100, 150, 200, and 250 ppm, variation in pH of dye 2,5,7,9 and 11. Measurement of the resulting concentration dye degradation using a UV-Vis Spectrophotometer with a wavelength of 319 nm. A ZnO-chitosan composite was found to degrade Indigosol Yellow IRK batik dye at 180 minutes (98.28%), optimum concentration of 150 ppm (98.06%), optimum pH of 9 (98.98%). The photodegradation effectiveness test of the ZnO-chitosan composite using effective UV light was 5.60% compared to ZnO-chitosan without UV light. It was concluded that the ZnO-chitosan composite could degrade the Indigosol Yellow IRK batik dye so that the ZnO-chitosan-UV composite was more effectively used as an environmentally friendly dye degrader.
References
Abdelhady, M.M. 2012. Preparation and Characterization of Chitosan/Zinc Oxide Nanoparticles for Importing Antimicrobial and UV Protection to Cotton Fabric. Internasional Journal of Carbohydrate Chemistrhy. ISSN:840-591. https://www.hindawi.com/journals/ijcc/2012/840591/
Agil, Muhammad dan Endang Sutaraningsih. 2016. Dekolorisasi Pewarna Indigosol oleh Bakteri Tanah. Prosiding Syambion (Symposium on Biology Education). ISSN: 2540-752x . http://symbion.pbio.uad.ac.id/prosiding/
Ali, R., and Siew, ooi Bon, 2008, Photodegradation of New Methylen Blue N in Aqueous Solution Using Zinc Oxide and Titanium Dioxide as Catalyst. Jurnal teknologi.45(F).hal. 31-42. https://www.researchgate.net/publication/242267396
Damayanti, Windi., Emma Rochima., dan Zahidah Hasan. 2016. Aplikasi Kitosan Sebagai Antibakteri Pada Filet Patin Selama Penyimpanan Suhu Rendah. JPHPI. Vol. 19 No. 3. https://www.researchgate.net/publication/322909237
Dhanavel, S., E A K Nivethaa., V Narayanan and A Stephen. 2014. Photocatalytic activity of Chitosan/ZnO nanocomposites for degrading methylene blue. International Journal of ChemTech Research. Vol.6, No.3, pp 1880-1882. https://www.researchgate.net/publication/263587380
Dini, Eka Ayu Putrid an Sri Wardani. 2014. Degradasi Metilen Biru Menggunakan Fotokatalis ZnO-Zeolit. Chem. Prog. Vol. 7, No.1. https://ejournal.unsrat.ac.id/v2/
Hasri. 2015. Studi Adsorpsi Logam Pb(II) Menggunakan Adsorben biomassa Aspergillus niger Hasil Pemerangkapan. Jurnal Sainsmat, Vol. IV, No. 2. ISSN 2086-6755. https://www.semanticscholar.org/paper/
Husna, Niki Rachmanur., Hasri., dan Sudding. 2017. Pengaruh Ph Terhadap Degradasi Pewarnadirect Blue Menggunakan Jamur Pelapuk Kayu (Pleurotus Flabellatus). Jurnal Kimia Riset. Vol. 2 No. 2. http://eprints.unm.ac.id/17317/
Kabra, K., R. Chaudhary, dan R. L. Sawhney. 2004. Treatment of Hazardous Organic and Inorganic Compounds Trough Aqueous-phase Photocatalysis: A Review, Ind. Eng. Chem. Res. 43, 7683-7696. https://www.researchgate.net/publication/231372715
Nugroho, Sigit., Agung Tri Prasetya., & Sri Wahyuni. 2013. Elektrodegradasi Indigosol Golden Yellow IRK dalam Limbah Batik dengan Elektoda Grafit. Indonesian Journal of Chemical Science. 2 (3). ISSN 2252-6951. https://www.semanticscholar.org/paper/
Rahmah, dan Surahma Asti Mulasari. 2015. Pengaruh Metode Koagulasi, Sedimentasi dan Variasi Filtrasi terhadap Penurunan Kadar TSS, COD dan Warna pada Limbah Cair Batik. Chemica. Vol. 2, No. 1. ISSN : 2355-875X. http://www.journal.uad.ac.id/index.php/
Sapawe, N., Jalil, A.A., Triwahyono, S., Sah, R.N.R.A., Jusoh, N.W.C., Hairom, N.H.H., & Efendi, J. 2013. Electrochemical Strategy for Grown ZnO Nanoparticles Deposited onto HY Zeolite with Enhanced Photodecolorization of Methylene Blue: Effect of the Formation of Si–O–Zn Bonds. Elsevier, 456, 144-158. https://www.sciencedirect.com/science/article/abs
Saraswati, I Gusti Ayu Adesia., Ni Putu Diantariani dan Putu Suarya. 2015. Fotodegradasi Zat Warna Tekstil Congo Red dengan Fotokatalis ZnO-Arang Aktif dan Sinar Ultraviolet (UV). Jurnal Kimia. ISSN: 1907-9850. https://www.researchgate.net/publication/291335994
Surono, Agustya Tri dan Heri Sutanto. 2014. Sifat Optik Zinc Oxide (ZnO) yang Dideposisi di Atas Substrat Kaca Menggunakan Metode Chemical Solution Deposition (CSD) dan Aplikasinya untuk Degradasi Zat Warn Methylene Blue. Youngster Physics Journal. Vol. 2, No. 1. ISSN: 2303-7371. https://www.neliti.com/publications/213748/
Sutanto, Heri., Eko Hidayanto., Muhammad Irwanto., Agus Romadhan., dan Yoyon Wahyono. 2017. Pengaruh Konsentrasi Doping Nitrogen (N) pada Material Fotokatalis Seng Oksida (ZnO) terhadap Degradasi Limbah Zat Pewarna Tekstil. Reaktor. Vol. 17, No. 1. ISSN: 2407-5973. https://ejournal.undip.ac.id/index.php/reaktor/article/view/13555
Tang, Lie-gui, David N, dan S. HON. 2001. Chelation of Chitosan Derivatives with Zinc Ions. II. Association Complexes of Zn2+ onto O,N-Carboxymethyl Chitosan. Journal of Applied Polymer Science, Vol. 79, 1476–1485. https://onlinelibrary.wiley.com/doi/10.1002/1097-4628(20010222)79:8%3C1476::AID-APP150%3E3.0.CO;2-A
Wismayanti Dewa Ayu, Ni Putu Diantariani dan Putu Suarya. 2015. Pembuatan Komposit ZnO-Arang Aktif Sebagai Fotokatalis untuk Mendegradasi Zat Warna Metilen Biru.Jurnal Kimia. ISSN: 1907-9850. https://ojs.unud.ac.id/index.php/jchem/article/view/15270
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