PYROLYSIS OF PALM OIL MILL EFFLUENT (POME) USING MODIFIED LAMPUNG NATURAL ZEOLITE WITH THE SI/AL RATIO OF 1 AS CATALYST

Authors

  • Kamisah Delilawati Pandiangan Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Frangky Gom Gom Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Nurul Fajriyati Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Muhammad Sabil Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Tasyadinia Tasyadinia Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Hanna Luthfia Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Qori Hikmah Faranida Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Ilim Ilim Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145
  • Wasinton Simanjuntak Department of Chemistry, FMIPA, University of Lampung, Jl. Prof. Dr. Ir. Sumantri Brojonegoro No. 1 Gedong Meneng, Rajabasa Bandar Lampung, Lampung 35145

DOI:

https://doi.org/10.23960/analit.v9i02.199

Keywords:

POME, pyrolysis, BCO, Lampung natural zeolite, catalyst

Abstract

In this research, palm oil mill effluent (POME), was pyrolized using a modified Lampung natural zeolite (LNZ) catalyst. Modification was conducted by reducing the Si/Al molar ratio to 1 by mixing certain mass of food grade aluminum food dissolved in 1.0 M NaOH solution and certain mass of LNZ. The mixture was homogenized using a magnetic stirrer, left at room temperature for 12 hours, and finally subjected to hydrothermal crystallization at 100 ºC for 72 hours. The solid sample produced was dried and calcined at 600 °C for 6 hours then characterized using X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) techniques to evaluate the formation of zeolite-A. The BCO produced from the pyrolysis experiment was analyzed using gas chromatography-mass spectrometry (GC-MS), revealing the presence of hydrocarbon as the main components (70%), suggesting the promising potential of the catalyst for further investigation.

References

Chen, D., Wang, Y., Liu, Y., Cen, K., Cao, X., Ma, Z., and Li, Y. (2019). Comparative Study on the Pyrolysis Behaviors of Rice Straw under Different Washing Pretreatments of Water, Acid Solution, and Aqueous Phase Bio-oil by Using TG-FTIR and PY-GC/MS. Fuel, 252, 1–9. https://doi.org/10.1016/j.fuel.2019.04.086
Duan, D., Zhang, Y., Lei, H., Villota, E., and Ruan, R. (2019). Renewable Jet- fuel Range Hydrocarbons Production from Co-pyrolysis of Lignin and Soapstock with the Activated Carbon Catalyst. Waste Management 88:1-9. https://doi.org/10.1016/j.wasman.2019.03.030

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Published

2024-11-13

Issue

Vol. 9, No. 02 October (2024) Analit : Analytical and Environmental Chemistry

Section

Articles

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Copyright (c) 2024 Kamisah Delilawati Pandiangan, Frangky Gom Gom, Nurul Fajriyati, Muhammad Sabil, Tasyadinia Tasyadinia, Hanna Luthfia, Qori Hikmah Faranida, Ilim Ilim, Wasinton Simanjuntak

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