SYNTHESIS OF CHITOSAN FROM KIJING SHELLS (P. exilis) WITH THE ADDITION OF CHLOROACETIC ACID AND TRIPOLYPHOSPHATE CROSS-LINKER FOR Cu (II) METAL ADSORPTION
DOI:
https://doi.org/10.23960/analit.v9i01.174Keywords:
Adsorption, Carboxymethyl Chitosan (CMCh)Abstract
The utilization of kijing clam shells as raw materials for chitosan production is one of the efforts to reduce kijing clam shell waste. This study is an experiment aimed at determining how to synthesize carboxymethyl chitosan (CM-Ch) and carboxymethyl chitosan-tripolyphosphate (CM-Ch-TPP), as well as the influence of pH and concentration of CM-Ch and CM-Ch-TPP on the adsorption of Cu(II) metal ions. The results showed that chitosan had a degree of deacetylation (DD) of 76%. Synthesized CM-Ch had characteristic functional groups at peaks 1610.56 cm-1 and 1425.4 cm-1. In the synthesized CM-Ch-TPP, there were functional groups at the peak of P=O stretch vibration and P-O stretch vibration at wave numbers 1213.23 cm-1 and 11,53.43 cm-1 in kijing. It is concluded that CM-Ch and CM-Ch-TPP have the ability to adsorb Cu(II) metal ions at pH 10 with concentrations ranging from 50 to 150 ppm.
The utilization of kijing clam shells as raw materials for chitosan production is one of the efforts to reduce kijing clam shell waste. This study is an experiment aimed at determining how to synthesize carboxymethyl chitosan (CM-Ch) and carboxymethyl chitosan-tripolyphosphate (CM-Ch-TPP), as well as the influence of pH and concentration of CM-Ch and CM-Ch-TPP on the adsorption of Cu(II) metal ions. The results showed that chitosan had a degree of deacetylation (DD) of 76%. Synthesized CM-Ch had characteristic functional groups at peaks 1610.56 cm-1 and 1425.4 cm-1. In the synthesized CM-Ch-TPP, there were functional groups at the peak of P=O stretch vibration and P-O stretch vibration at wave numbers 1213.23 cm-1 and 11,53.43 cm-1 in kijing. It is concluded that CM-Ch and CM-Ch-TPP have the ability to adsorb Cu(II) metal ions at pH 10 with concentrations ranging from 50 to 150 ppm.
References
Agustina, Sry, I Made Dira Swantara1, and I Nyoman Suartha (2015). Isolasi Kitin, Karakterisasi, Dan Sintesis Kitosan Dari Kulit Udang. Jurnal Kimia. 9(2).
Akbar, Muhammad Kamal, Edison, and Andarini (2021). Deproteinasi Kitin Cangkang Kerang Kijing (Pilsbryoconcha Exilis) Dengan Enzim Papain. Frontiersin Neuroscience,.
Alauhdin, M. and N Widiarti. (2014). Sintesis Dan Modifikasi Lapis Tipis Kitosan-Tripolifosfat. Jurnal MIPA. 37 (1).
Dompempein, Edward J.. (2017). Isolasi Dan Identifikasi Kitin Dan Kitosan Dari Kulit Udang Windu (Penaeus Monodon) Dengan Spektroskopi Inframera. Majalah BIAM.13 (01).
Faiz, Muhamad Ziaul, Agus Sabdono, and Ambariyanto. (2013). Kandungan Logam Berat Timbal (Pb) dan Tembaga (Cu) pada Karang Pocillopora damicornis di Perairan Taman Nasional Karimunjawa. Journal Of Marine Research. 2(1).
Handayani, Lia, Faisal Syahputra, and Yayuk Astuti. (2018). Utilization and Characterization of Oyster Shell as Chitosan and Nanochitosan. Journal of Scientific and Applied Chemistry. 22 (4): 224-231. https://doi.org/10.14710/jksa.21.4.224-231.
Hasanah, Rizka Nurul, Lely Kurniawati, and Murniati, (2018). Modifikasi Kitosan Dari Limbah Cangkang Rajungan Dengan Crosslinking Menggunakan Glutaraldehida Sebagai Adsorben Ion Logam Cu(II). (II):1-12
Hasri, (2010). Prospek Kitosan Dan Kitosan Termodifikasi Sebagai Biopolimer Alami Yang Menjanjikan, Jurnal Chemica .11(2).DOI:https://doi.org/10.35580/CHEMICA.V11I2.490">10.35580/CHEMICA.V11I2.490
Hasri and Rizky Oktariani. (2015). Blending Kitin - Aspergillus niger untuk Adsorpsi Ion Logam Cu(II). Jurnal Chemica. 16(1).DOI:https://doi.org/10.35580/CHEMICA.V16I1.4549">10.35580/CHEMICA.V16I1.4549
Jin, Xu, Kai Li, Ping Ning, Shuangyou Bao,and Lihong Tang. (2017). Removal of Cu(II) Ions from Aqueous Solution by Magnetic Chitosan-Tripolyphosphate Modified Silica-Coated Adsorbent: Characterization and Mechanisms. Water Air Soil Pollut. 228 (8): 302. DOI 10.1007/s11270-017-3482-6.
Lusiana, Retno Ariadi, and Wahyu Putri Pranotoningtyas. (2018). Membran Kitosan Termodifikasi Tripolifosfat-Heparin dan Aplikasinya pada Permeasi Urea dan Kreatinin. Jurnal Analit: Analytical and Environmental Chemistry. 3(1). DOI: http://dx.doi.org/10.23960/aec.v3.i1.2018.p11-21
Mouryaa, V.K. Nazma N. Inamdar and Ashutosh Tiwari (2010). Carboxymethyl chitosan and Its Application. Adv. Mat. Lett. 1(1), 11-33. DOI: 10.5185/amlett.2010.3108
Nucifera, Irene Frinanda, Titin Anita Zaharah, and Intan Syahbanu. (2016). Uji Stabilitas Kitosan-Kaolin Sebagai Adsorben Logam Berat Cu(II) Dalam Air. JKK, 5(2).
Sari, Frederica Giofany, Diky Hidayat and Dian Septiani P.. (2016). Kajian Kandungan Logam Berat Mangan (Mn) dan Nikel (Ni) pada Sedimen di Pesisir Teluk Lampung. Jurnal Analit: Analytical and Environmental Chemistry. 1(1). DOI: http://dx.doi.org/10.23960%2Faec.v1i1.2016.p
Silverstein, Robert M., and Francis X. Webster. (1998). Spectrometric Identification of Organic Compound (6th Ed). New York: John Wiley and Sons Inc.
Solikha, Dian Farkhatus. (2019). Penentuan Kadar Tembaga (II) Pada Sampel Menggunakan Spektroskopi Serapan Atom (Ssa) Perkin Erlmer Analyst 100 Metode Kurva Kalibrasi. Syntax Literate : Jurnal Ilmiah Indonesia. 4(2). DOI:10.36418/syntax-literate.v4i2.594.
Suseno, Natalia, Karsono S. Padmawijaya, Nico C.L., Harry, (2018). Synthesis of Soluble Carboxymethyl Chitosan from Low Molecular Weight of Chitosan. Prosiding Seminar Nasional Teknik Kimia “Kejuangan”.
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